Beilstein J. Org. Chem.2012,8, 897–904, doi:10.3762/bjoc.8.102
experts only. As an example, we here focus in on the recent synthesis of multicomponent photosystems with antiparallel charge-transfercascades in co-axial hole- and electron-transporting channels. The synthetic steps are described one-by-one, starting with commercial starting materials and moving on to
fill them with functional π-stacks of free choice.
Keywords: asparagusic acid; charge-transfercascades; chromophores; disulfide exchange; hydrazone exchange; molecular switches; naphthalenediimides; π-stacks; surface-initiated polymerization; Introduction
The architecture of photosystem 1 is rather
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Graphical Abstract
Figure 1:
Schematic structure of photosystem 1 on indium tin oxide (ITO, grey) with antiparallel gradients in...